International Chemical Safety Cards AMINOCARB ICSC: 0097 4-Dimethylamino-m-tolyl N-methylcarbamate 4-Dimethylamine m-cresyl methylcarbamate C11H16N2O2 Molecular mass: 208.3 ICSC #    0097 CAS #     2032-59-9 RTECS # FC0175000 UN #        2757 EC #         006-018-00-5 April 22, 1994 Peer reviewe TYPES OF HAZARD/ EXPOSURE ACUTE HAZARDS/ SYMPTOMS PREVENTION FIRST AID/ FIRE FIGHTING FIRE Combustible. Liquid formulations containing organic solvents may be flammable. Gives off irritating or toxic fumes (or gases) in a fire. NO open flames. Powder, water spray, foam, carbon dioxide. EXPLOSION Risk of fire and explosion if formulations contain flammable/explosive solvents. EXPOSURE AVOID ALL CONTACT! AVOID EXPOSURE OF ADOLESCENTS AND CHILDREN! IN ALL CASES CONSULT A DOCTOR!  •INHALATION Dizziness. Sweating. Laboured breathing. Unconsciousness. Vomiting. Pupillary constriction, muscle cramp, excessive salivation. Ventilation (not if powder). Local exhaust or breathing protection. Fresh air, rest. Half-upright position. Refer for medical attention.  •SKIN MAY BE ABSORBED! (Further see Inhalation). Protective gloves. Protective clothing. Remove contaminated clothes. Rinse and then wash skin with water and soap. Refer for medical attention. (See Notes).  •EYES Face shield or eye protection in combination with breathing protection if powder. First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.  •INGESTION Abdominal cramps. Diarrhoea. Nausea. Vomiting. (Further see Inhalation). Do not eat, drink, or smoke during work. Wash hands before eating. Rinse mouth. Give a slurry of activated charcoal in water to drink. Induce vomiting (ONLY IN CONSCIOUS PERSONS!). Rest. Refer for medical attention. See Notes. SPILLAGE DISPOSAL STORAGE PACKAGING & LABELLING Do NOT wash away into sewer. Sweep spilled substance into containers; if appropriate, moisten first to prevent dusting. Carefully collect remainder, then remove to safe place. Personal protection: P3 filter respirator for toxic particles. Do NOT let this chemical enter the environment. Provision to contain effluent from fire extinguishing. Separated from food and feedstuffs . Do not transport with food and feedstuffs. Marine pollutant. T symbol N symbol R: 24/25-50/53 S: 1/2-28-36/37-45-60-61 UN Hazard Class: 6.1 UN Packing Group: II SEE IMPORTANT INFORMATION ON BACK ICSC: 0097 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities (C) IPCS CEC 1994. No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and NIOSH IDLH values.

International Chemical Safety Cards AMINOCARB ICSC: 0097 I M P O R T A N T D A T A PHYSICAL STATE; APPEARANCE: WHITE CRYSTALS. PHYSICAL DANGERS: CHEMICAL DANGERS: The substance decomposes on heating producing toxic fumes and irritating fumes including nitrogen oxides . OCCUPATIONAL EXPOSURE LIMITS: TLV not established. ROUTES OF EXPOSURE: The substance can be absorbed into the body by inhalation, through the skin and by ingestion. INHALATION RISK: Evaporation at 20°C is negligible; a harmful concentration of airborne particles can, however, be reached quickly on spraying or when dispersed, especially if powdered. EFFECTS OF SHORT-TERM EXPOSURE: The substance may cause effects on the nervous system , resulting in convulsions , respiratory failure . Cholinesterase inhibitor. Exposure may result in death. The effects may be delayed. Medical observation is indicated. EFFECTS OF LONG-TERM OR REPEATED EXPOSURE: The substance may have effects on the nervous system , liver . PHYSICAL PROPERTIES Melting point: 93°C Solubility in water, g/100 ml at 20°C: 0.09 Vapour pressure, Pa at 20°C: 0.0023 Relative vapour density (air = 1): 7.18 Relative density of the vapour/air-mixture at 20°C (air = 1): 1 Octanol/water partition coefficient as log Pow: 1.73 ENVIRONMENTAL DATA This substance may be hazardous to the environment; special attention should be given to mammals, birds, honey bees, water organisms. N O T E S Depending on the degree of exposure, periodic medical examination is suggested. Specific treatment is necessary in case of poisoning with this substance; the appropriate means with instructions must be available. Carrier solvents used in commercial formulations may change physical and toxicological properties. Do NOT take working clothes home. Bayer 44646, Metacil, Matacil, Mitacil are trade names. If the substance is formulated with solvents also consult the ICSCs of these materials. Card has been partly updated in April 2005. See sections Occupational Exposure Limits, EU classification. Transport Emergency Card: TEC (R)-61GT7-II ADDITIONAL INFORMATION ICSC: 0097 AMINOCARB (C) IPCS, CEC, 1994

IMPORTANT LEGAL NOTICE: Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.