International Chemical Safety Cards AMITRAZ ICSC: 0098 N-Methylbis(2,4-xylyliminomethyl)amine N,N'-(Methyliminodimethylidyne)bis-2,4-xylidine C19H23N3 Molecular mass: 293.4 ICSC #    0098 CAS #     33089-61-1 RTECS # ZF0480000 EC #         612-086-00-2 April 22, 1994 Peer reviewe TYPES OF HAZARD/ EXPOSURE ACUTE HAZARDS/ SYMPTOMS PREVENTION FIRST AID/ FIRE FIGHTING FIRE Combustible. Liquid formulations containing organic solvents may be flammable. Gives off irritating or toxic fumes (or gases) in a fire. NO open flames. Powder, water spray, foam, carbon dioxide. EXPLOSION EXPOSURE STRICT HYGIENE! AVOID EXPOSURE OF ADOLESCENTS AND CHILDREN!  •INHALATION (See Ingestion). Ventilation (not if powder). Fresh air, rest. Refer for medical attention.  •SKIN MAY BE ABSORBED! Transient skin flushing. (Further see Inhalation). Protective gloves. Protective clothing. Remove contaminated clothes. Rinse and then wash skin with water and soap. Refer for medical attention.  •EYES Safety spectacles. First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.  •INGESTION Slow heart beat. Low blood pressure. Sedation. Low body temperature. Do not eat, drink, or smoke during work. Wash hands before eating. Rinse mouth. Refer for medical attention. See Notes. SPILLAGE DISPOSAL STORAGE PACKAGING & LABELLING Do NOT wash away into sewer. Sweep spilled substance into containers; if appropriate, moisten first to prevent dusting. Carefully collect remainder, then remove to safe place. (Extra personal protection: P2 filter respirator for harmful particles). Provision to contain effluent from fire extinguishing. Xn symbol R: 22 S: 2-22 SEE IMPORTANT INFORMATION ON BACK ICSC: 0098 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities (C) IPCS CEC 1994. No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and NIOSH IDLH values.

International Chemical Safety Cards AMITRAZ ICSC: 0098 I M P O R T A N T D A T A PHYSICAL STATE; APPEARANCE: COLOURLESS CRYSTALS. PHYSICAL DANGERS: CHEMICAL DANGERS: The substance decomposes on burning producing toxic fumes including nitrogen oxides. OCCUPATIONAL EXPOSURE LIMITS: TLV not established. ROUTES OF EXPOSURE: The substance can be absorbed into the body by inhalation, through the skin and by ingestion. INHALATION RISK: Evaporation at 20°C is negligible; a harmful concentration of airborne particles can, however, be reached quickly on spraying or when dispersed, especially if powdered. EFFECTS OF SHORT-TERM EXPOSURE: The substance may cause effects on the central nervous system. EFFECTS OF LONG-TERM OR REPEATED EXPOSURE: The substance may have effects on the central nervous system and liver. PHYSICAL PROPERTIES Melting point: 86°C Relative density (water = 1): 1.1 Solubility in water: none Vapour pressure, Pa at 20°C: very low ENVIRONMENTAL DATA This substance may be hazardous to the environment; special attention should be given to fish. N O T E S If the pesticide is present under the form of a formulation containing hydrocarbon solvents, vomiting may not be induced. Insufficient data are available on the effect of this substance on human health, therefore utmost care must be taken. Carrier solvents used in commercial formulations may change physical and toxicological properties. If the pesticide is formulated with an organic solvent, also consult ICSC of the solvent used. Acarac, Acadrex, Azodieno, Baam, Bumetran, Danicut, Ectodex, Edrizar, Istambul, Maitac, Mitac, Ovasyn, Taktic, Triatix, Triatox, Topline and Tudy are trade names. ADDITIONAL INFORMATION ICSC: 0098 AMITRAZ (C) IPCS, CEC, 1994

IMPORTANT LEGAL NOTICE: Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.