International Chemical Safety Cards PERMETHRIN ICSC: 0312 3-Phenoxybenzyl (1RS)-cis-trans-3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylate (3-Phenoxyphenyl)methyl 3-(2,2-dichloroethenyl)-2,2-dimethylcyclopropanecarboxylate C21H20Cl2O3 Molecular mass: 391.3 ICSC #    0312 CAS #     52645-53-1 RTECS # GZ1255000 UN #        3352 EC #         613-058-00-2 March 13, 2001 Peer reviewed TYPES OF HAZARD/ EXPOSURE ACUTE HAZARDS/ SYMPTOMS PREVENTION FIRST AID/ FIRE FIGHTING FIRE Combustible. Liquid formulations containing organic solvents may be flammable. Gives off irritating or toxic fumes (or gases) in a fire. NO open flames. Powder, AFFF, foam, carbon dioxide. EXPLOSION In case of fire: keep drums, etc., cool by spraying with water. EXPOSURE PREVENT DISPERSION OF DUST!  •INHALATION Cough. Ventilation, local exhaust, or breathing protection. Fresh air, rest.  •SKIN Redness. Burning sensation. Protective gloves. Protective clothing. Remove contaminated clothes. Rinse and then wash skin with water and soap.  •EYES Redness. Pain. Face shield. First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.  •INGESTION Burning sensation. Diarrhoea. Vomiting. Do not eat, drink, or smoke during work. Wash hands before eating. Rinse mouth. Refer for medical attention. SPILLAGE DISPOSAL STORAGE PACKAGING & LABELLING Do NOT wash away into sewer. Do NOT let this chemical enter the environment. Sweep spilled substance into containers; if appropriate, moisten first to prevent dusting. Carefully collect remainder, then remove to safe place. (Extra personal protection: A/P2 filter respirator for organic vapour and harmful dust.) Provision to contain effluent from fire extinguishing. Separated from food and feedstuffs . Keep in a well-ventilated room. Do not transport with food and feedstuffs. Xn symbol R: 22 S: (2) UN Hazard Class: 6.1 UN Packing Group: III SEE IMPORTANT INFORMATION ON BACK ICSC: 0312 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities (C) IPCS CEC 1994. No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and NIOSH IDLH values.

International Chemical Safety Cards PERMETHRIN ICSC: 0312 I M P O R T A N T D A T A PHYSICAL STATE; APPEARANCE: YELLOW BROWN TO BROWN VISCOUS LIQUID OR CRYSTALS. PHYSICAL DANGERS: CHEMICAL DANGERS: The substance decomposes on burning producing toxic fumes including hydrogen chloride. OCCUPATIONAL EXPOSURE LIMITS: TLV not established. ROUTES OF EXPOSURE: The substance can be absorbed into the body by inhalation of its aerosol and by ingestion. INHALATION RISK: No indication can be given about the rate in which a harmful concentration in the air is reached on evaporation of this substance at 20°C. EFFECTS OF SHORT-TERM EXPOSURE: The substance is irritating to the eyes , the skin and the respiratory tract . EFFECTS OF LONG-TERM OR REPEATED EXPOSURE: PHYSICAL PROPERTIES Melting point: 34-39°C Relative density (water = 1): 1.2 Solubility in water: none Vapour pressure, Pa at 20°C: <10 Octanol/water partition coefficient as log Pow: 6.5 ENVIRONMENTAL DATA The substance is very toxic to aquatic organisms. Avoid release to the environment in circumstances different to normal use. N O T E S Carrier solvents used in commercial formulations may change physical and toxicological properties. Ambush, Eksmin, Talcord are trade names. Also consult publication Health and Safety Guide No. 33 Permethrin, and Environmental Health Criteria No. 94 Permethrin, of IPCS. Transport Emergency Card: TEC (R)-61G43c ADDITIONAL INFORMATION ICSC: 0312 PERMETHRIN (C) IPCS, CEC, 1994

IMPORTANT LEGAL NOTICE: Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.