International Chemical Safety Cards

TRIISOPROPANOLAMINE ICSC: 0592

Tri-2-propanolamine
Tris(2-hydroxypropyl)amine
1,1',1-Nitrilotripropan-2-ol
C9H21NO3 / (CH3CHOHCH2)3N
Molecular mass: 191.3
ICSC #    0592
CAS #     122-20-3
RTECS # UB8750000
EC #         603-097-00-3
March 28, 1996 Peer reviewed
TYPES OF HAZARD/ EXPOSURE ACUTE HAZARDS/ SYMPTOMS PREVENTION FIRST AID/
FIRE FIGHTING
FIRE Combustible. Gives off irritating or toxic fumes (or gases) in a fire.
NO open flames.
Powder, alcohol-resistant foam, water spray, carbon dioxide.
EXPLOSION


EXPOSURE
AVOID ALL CONTACT!
IN ALL CASES CONSULT A DOCTOR!
 •INHALATION Sore throat. Cough. Burning sensation. Shortness of breath. Symptoms may be delayed (see Notes).
Ventilation, local exhaust, or breathing protection.
Fresh air, rest. Half-upright position. Artificial respiration may be needed. Refer for medical attention.
 •SKIN Pain. Blisters.
Protective gloves. Protective clothing.
Rinse and then wash skin with water and soap. Refer for medical attention.
 •EYES Redness. Pain. Severe deep burns.
Safety goggles.
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
 •INGESTION Abdominal pain. Burning sensation. Shock or collapse.
Do not eat, drink, or smoke during work.
Rinse mouth. Do NOT induce vomiting. Refer for medical attention.
SPILLAGE DISPOSAL STORAGE PACKAGING & LABELLING
Personal protection: P2 filter respirator for harmful particles. Sweep spilled substance into containers; if appropriate, moisten first to prevent dusting. Carefully collect remainder, then remove to safe place.
Separated from strong oxidants, strong acids.

Xi symbol
R: 36-52/53
S: 2-26-61
SEE IMPORTANT INFORMATION ON BACK
ICSC: 0592 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities (C) IPCS CEC 1994. No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and NIOSH IDLH values.

International Chemical Safety Cards

TRIISOPROPANOLAMINE ICSC: 0592
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PHYSICAL STATE; APPEARANCE:
WHITE HYGROSCOPIC CRYSTALS.

PHYSICAL DANGERS:


CHEMICAL DANGERS:
The substance decomposes on heating or on burning producing toxic fumes including nitrogen oxides . The solution in water is a medium strong base. Reacts with strong oxidants and strong acids .

OCCUPATIONAL EXPOSURE LIMITS:
TLV not established.
MAK not established.


ROUTES OF EXPOSURE:
The substance can be absorbed into the body by inhalation of its aerosol and by ingestion.

INHALATION RISK:
Evaporation at 20°C is negligible; a harmful concentration of airborne particles can, however, be reached quickly.

EFFECTS OF SHORT-TERM EXPOSURE:
The substance is corrosive to the eyes, the skin and the respiratory tract. Inhalation of dust may cause lung oedema (see Notes). The effects may be delayed. Medical observation is indicated.

EFFECTS OF LONG-TERM OR REPEATED EXPOSURE:
PHYSICAL
PROPERTIES
Boiling point: 305°C
Melting point: 45°C
Density: 1
g/cm3
Solubility in water, g/100 ml at 20°C: 83
(good)
Vapour pressure, Pa at 20°C: negligible
Flash point: 160°C o.c.
Auto-ignition temperature: 320°C
ENVIRONMENTAL
DATA

N O T E S
The symptoms of lung oedema often do not become manifest until a few hours have passed and they are aggravated by physical effort. Rest and medical observation are therefore essential. Immediate administration of an appropriate inhalation therapy by a doctor or a person authorized by him/her, should be considered.
NFPA Code: H2; F1; R0
ADDITIONAL INFORMATION


ICSC: 0592 TRIISOPROPANOLAMINE
(C) IPCS, CEC, 1994
IMPORTANT LEGAL NOTICE: Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.