International Chemical Safety Cards ISOHEPTANE ICSC: 0658 2-Methylhexane C7H16 / CH3CH(CH3)(CH2)3CH3 Molecular mass: 100.2 ICSC #    0658 CAS #     591-76-4 RTECS # MO3871500 UN #        1206 (heptanes) EC #         601-008-00-2 October 09, 2002 Peer reviewed TYPES OF HAZARD/ EXPOSURE ACUTE HAZARDS/ SYMPTOMS PREVENTION FIRST AID/ FIRE FIGHTING FIRE Highly flammable. NO open flames, NO sparks, and NO smoking. NO water. Alcohol-resistant foam, powder, carbon dioxide. EXPLOSION Vapour/air mixtures are explosive. Closed system, ventilation, explosion-proof electrical equipment and lighting. Prevent build-up of electrostatic charges (e.g., by grounding). Do NOT use compressed air for filling, discharging, or handling. In case of fire: keep drums, etc., cool by spraying with water. EXPOSURE  •INHALATION Headache. Nausea. Vomiting. Dizziness. Ventilation, local exhaust, or breathing protection. Fresh air, rest.  •SKIN Dry skin. Protective gloves. Remove contaminated clothes. Rinse and then wash skin with water and soap.  •EYES Safety spectacles. First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.  •INGESTION (Further see Inhalation). Do not eat, drink, or smoke during work. Rinse mouth. Do NOT induce vomiting. SPILLAGE DISPOSAL STORAGE PACKAGING & LABELLING Evacuate danger area! Remove all ignition sources. Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in sand or inert absorbent and remove to safe place. Do NOT wash away into sewer. (Extra personal protection: filter respirator for organic gases and vapours.) Fireproof. Separated from strong oxidants. Note: C F symbol Xn symbol N symbol R: 11-38-50/53-65-67 S: 2-9-16-29-33-60-61-62 UN Hazard Class: 3 UN Packing Group: II SEE IMPORTANT INFORMATION ON BACK ICSC: 0658 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities (C) IPCS CEC 1994. No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and NIOSH IDLH values.

International Chemical Safety Cards ISOHEPTANE ICSC: 0658 I M P O R T A N T D A T A PHYSICAL STATE; APPEARANCE: COLOURLESS LIQUID , WITH CHARACTERISTIC ODOUR. PHYSICAL DANGERS: The vapour is heavier than air and may travel along the ground; distant ignition possible. As a result of flow, agitation, etc., electrostatic charges can be generated. CHEMICAL DANGERS: Heating may cause violent combustion or explosion. Reacts with strong oxidants. OCCUPATIONAL EXPOSURE LIMITS: TLV not established. ROUTES OF EXPOSURE: The substance can be absorbed into the body by inhalation of its vapour and by ingestion. INHALATION RISK: No indication can be given about the rate in which a harmful concentration in the air is reached on evaporation of this substance at 20°C. EFFECTS OF SHORT-TERM EXPOSURE: If this liquid is swallowed, aspiration into the lungs may result in chemical pneumonitis. The substance may cause effects on the central nervous system at high levels . EFFECTS OF LONG-TERM OR REPEATED EXPOSURE: The liquid defats the skin. PHYSICAL PROPERTIES Boiling point: 90°C Melting point: -118°C Relative density (water = 1): 0.68 Solubility in water: none Vapour pressure, kPa at 14.9°C: 5.3 Relative vapour density (air = 1): 3.4 Relative density of the vapour/air-mixture at 20°C (air = 1): 1.13 Flash point: -18°C c.c. Auto-ignition temperature: 220°C Explosive limits, vol% in air: 1.0-6.0 ENVIRONMENTAL DATA N O T E S NFPA Code: H0; F3; R0; Transport Emergency Card: TEC (R)-30S1206 ADDITIONAL INFORMATION ICSC: 0658 ISOHEPTANE (C) IPCS, CEC, 1994

IMPORTANT LEGAL NOTICE: Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.