International Chemical Safety Cards DICYCLOHEXYLAMINE ICSC: 1339 N,N-Dicyclohexylamine N-Cyclohexylcyclohexanamine Dodecahydrodiphenylamine C12H23N / C6H11NHC6H11 Molecular mass: 181.4 ICSC #    1339 CAS #     101-83-7 RTECS # HY4025000 UN #        2565 EC #         612-066-00-3 October 18, 1999 Peer reviewed TYPES OF HAZARD/ EXPOSURE ACUTE HAZARDS/ SYMPTOMS PREVENTION FIRST AID/ FIRE FIGHTING FIRE Combustible. Gives off irritating or toxic fumes (or gases) in a fire. NO open flames. Powder, alcohol-resistant foam, water spray, carbon dioxide. EXPLOSION In case of fire: keep drums, etc., cool by spraying with water. EXPOSURE AVOID ALL CONTACT! IN ALL CASES CONSULT A DOCTOR!  •INHALATION Sore throat. Cough. Burning sensation. Shortness of breath. Laboured breathing. Symptoms may be delayed (see Notes). Ventilation, local exhaust, or breathing protection. Fresh air, rest. Half-upright position. Artificial respiration may be needed. Refer for medical attention.  •SKIN Pain. Redness. Blisters Skin burns. Protective gloves. Protective clothing. Remove contaminated clothes. Rinse skin with plenty of water or shower. Refer for medical attention.  •EYES Pain. Redness. Severe deep burns. Face shield. First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.  •INGESTION Burning sensation. Abdominal pain. Shock or collapse. Do not eat, drink, or smoke during work. Rinse mouth. Do NOT induce vomiting. Refer for medical attention. SPILLAGE DISPOSAL STORAGE PACKAGING & LABELLING Collect leaking liquid in sealable containers. Cautiously neutralize remainder. Then wash away with plenty of water. Personal protection: complete protective clothing including self-contained breathing apparatus. Do NOT let this chemical enter the environment. Separated from strong oxidants, strong acids, food and feedstuffs . Do not transport with food and feedstuffs. C symbol N symbol R: 22-34-50/53 S: 1/2-26-36/37/39-45-60-61 UN Hazard Class: 8 UN Packing Group: III SEE IMPORTANT INFORMATION ON BACK ICSC: 1339 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities (C) IPCS CEC 1994. No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and NIOSH IDLH values.

International Chemical Safety Cards DICYCLOHEXYLAMINE ICSC: 1339 I M P O R T A N T D A T A PHYSICAL STATE; APPEARANCE: COLOURLESS LIQUID , WITH CHARACTERISTIC ODOUR. PHYSICAL DANGERS: CHEMICAL DANGERS: The substance decomposes on burning producing toxic fumes including nitrogen oxides . The substance is a strong base, it reacts violently with acid and is corrosive. Reacts with strong oxidants. OCCUPATIONAL EXPOSURE LIMITS: TLV not established. MAK: IIb (not established but data is available) skin absorption (H); (DFG 2004). ROUTES OF EXPOSURE: The substance can be absorbed into the body by inhalation of its vapour and by ingestion. INHALATION RISK: No indication can be given about the rate in which a harmful concentration in the air is reached on evaporation of this substance at 20°C. EFFECTS OF SHORT-TERM EXPOSURE: The substance is corrosive to the eyes, the skin and the respiratory tract. Inhalation of vapour may cause lung oedema (see Notes). The effects may be delayed. Medical observation is indicated. EFFECTS OF LONG-TERM OR REPEATED EXPOSURE: PHYSICAL PROPERTIES Boiling point: 256°C Melting point: -0.1°C Relative density (water = 1): 0.9 Solubility in water, g/100 ml at 25°C: 0.08 Vapour pressure, kPa at 37.7°C: 1.6 Relative vapour density (air = 1): 6.25 Flash point: 105°C o.c. Auto-ignition temperature: 255°C Explosive limits, vol% in air: 0.9-6.9 Octanol/water partition coefficient as log Pow: 3.5 ENVIRONMENTAL DATA The substance is harmful to aquatic organisms. N O T E S The symptoms of lung oedema often do not become manifest until a few hours have passed and they are aggravated by physical effort. Rest and medical observation is therefore essential. Immediate administration of an appropriate inhalation therapy by a doctor or a person authorized by him/her, should be considered. Card has been partly updated in April 2005. See sections Occupational Exposure Limits, Emergency Response. Transport Emergency Card: TEC (R)-80GC7-II+III NFPA Code: H3; F1; R0; ADDITIONAL INFORMATION ICSC: 1339 DICYCLOHEXYLAMINE (C) IPCS, CEC, 1994

IMPORTANT LEGAL NOTICE: Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.